The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Organics (N-compounds) / Peroxynitrates / CF3CF2CF2O2NO2 / Bossolasco(2012)_283K_200-290nm

DATAFILE: CF3CF2CF2O2NO2_Bossolasco(2012)_283K_200-290nm.txt
NAME: heptafluoropropyl peroxynitrate
FORMULA: CF3CF2CF2O2NO2
AUTHOR(YEAR): Bossolasco(2012)
T: 283K
λ: 200-290nm
BIBLIOGRAPHY: A.G. Bossolasco, F.E. Malanca, M.A. Burgos Paci, and G.A. Argüello, "Mechanism of photo-oxidation of heptafluorobutyric anhydride in the presence of NO2. Synthesis and characterization of heptafluoropropyl peroxynitrate, CF3CF2CF2OONO2", J. Phys. Chem. A 116, 9904-9910 (2012); DOI: 10.1021/jp307172g
COMMENTS: CF3CF2CF2O2NO2 was synthesized from the photolysis of heptafluorobutyric anhydride (CF3CF2CF2C(O))2O at 254 nm, in presence of NO2 and O2

The absorption cross sections were obtained from measurements of absorbances A at 300 K, according to

σ(cm2 molecule-1) = [A × T(K) × 31.7 × 10-20] / [p(mbar) × l(cm)]

where p, T, and l denote pressure, temperature, and absorption path length (the pressures of CF3CF2CF2O2NO2 ranged from 0.5 to 3.0 mbar)

The listed absorption cross sections are averages over 5-nm intervals

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